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	~~Adolph Garica is his name~~ and ~~the man totally loves this identity~~. ~~Dispatching is how he [http://browse.deviantart.com/?q=supports supports] his family members members. It~~'~~s not a common thing but what I spend time doing is bird keeping~~ and I'm ~~trying to create it a [http://www.dict.cc/?s=profession profession]. For years he's been a really enjoyable Florida. Go to~~ my ~~website much more out more: http://cosmewiki.org/index~~.~~php?title=%E5%88%A9%E7%94%A8%E8%80%85:BrodieU01ttx~~<br><br>~~Feel free to visit~~ my ~~blog ::~~ [http://~~cosmewiki~~.~~org~~/~~index~~.~~php?title=%E5%88%A9%E7%94%A8%E8%80%85:BrodieU01ttx dustin diamond~~]		I'm Summer and I live in a seaside city in northern Australia, South Maclean. I'm 39 and I'm will soon finish my study at Japanese Studies.<br><br>my website; [http://www.windsorstar.com/entertainment/Photos+Celebrities+loose/4010383/story.html Jason Hope christmas party]

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	~~'''Optical rotation (optical activity)'''~~ is the turning of the plane of [[Linear polarization\|linearly polarized]] [[light]] about the direction of motion as the light travels through certain materials. It occurs in solutions of [[chirality (chemistry)\|chiral]] molecules such as [[sucrose]] (sugar), solids with rotated [[crystal]] planes such as [[quartz]], and ~~[[Spin polarization\|spin-polarized]] gases of atoms or molecules. It is used in~~ the [[sugar]] industry to measure syrup concentration, in [[optics]] to manipulate [[Polarization (waves)\|polarization]], in [[chemistry]] to characterize substances in solution, and in [[optical mineralogy]] to help identify certain minerals in thin sections. It is ~~being developed as a method to measure~~ [~~[blood sugar]] concentration in [[diabetes\|diabetic]] people.~~		Adolph Garica is his name and the man totally loves this identity. Dispatching is how he [http://browse.deviantart.com/?q=supports supports] his family members members. It's not a common thing but what I spend time doing is bird keeping and I'm trying to create it a [http://www.dict.cc/?s=profession profession]. For years he's been a really enjoyable Florida. Go to my website much more out more: http://cosmewiki.org/index.php?title=%E5%88%A9%E7%94%A8%E8%80%85:BrodieU01ttx<br><br>Feel free to visit my blog :: [http://cosmewiki.org/index.php?title=%E5%88%A9%E7%94%A8%E8%80%85:BrodieU01ttx dustin diamond]

	~~== History ==~~
	~~[[Image~~:~~TartrateCrystal~~.~~svg\|200px\|thumb\|The two asymmetric crystals forms, dextrorotatory and levorotatory, of [[tartaric acid]]~~.]]
	~~The rotation of the orientation of linearly polarized light was first observed in 1811 in [[quartz]] by French physicist [[François Jean Dominique Arago]]~~. ~~Around this same~~ time~~, [[Jean Baptiste Biot]] also observed the effect in liquids~~ and gases of organic substances such as [[turpentine]]. In 1822, the English astronomer [[John Herschel\|Sir John F.W. Herschel]] discovered that different crystal forms of quartz rotate the linear polarization in different directions. Simple [[polarimeter]]s have been used since this time to measure the concentrations of simple sugars, such as [[glucose]], in solution. In fact, one name for glucose, '~~'dextrose'', refers~~ to ~~the fact that~~ it ~~causes linearly polarized light to rotate to the right or~~ [~~[wiktionary~~:~~dexter\|dexter]] side~~. ~~In a similar manner, levulose, more commonly known as [[fructose]], causes the plane of polarization to rotate to the left~~. ~~Fructose is even more strongly levorotatory than glucose is dextrorotatory. [[Inverted sugar syrup\|Invert sugar syrup]], commercially formed by the [[hydrolysis~~]] of [[sucrose]] syrup to a mixture of the component simple sugars, fructose, and glucose, gets its name from the fact that the conversion causes the direction of rotation to "invert" from right to left.

	In 1849, [[Louis Pasteur]] resolved a problem concerning the nature of [[tartaric acid]]. A solution of this compound derived from living things (to be specific, [[Lees (fermentation)\|wine lees]]) rotates the plane of [[Polarization (waves)\|polarization]] of light passing through it, but tartaric acid derived by [[chemical synthesis]] has no such effect, even though its reactions are identical and its elemental composition is the same. Pasteur noticed that the crystals come in two asymmetric forms that are mirror images of one another. Sorting the crystals by hand gave two forms of the compound: Solutions of one form rotate polarized light clockwise, while the other form rotate light counterclockwise. An equal mix of the two has no polarizing effect on light. Pasteur deduced that the molecule in question is asymmetric and could exist in two different forms that resemble one another as would left- and right-hand gloves, and that the organic form of the compound consists of purely the one type.

	~~In 1874, [[Jacobus Henricus van~~ 't Hoff]] and [[Joseph Achille Le Bel]] independently proposed that the phenomenon of optical activity could be explained by assuming that the chemical bonds between carbon atoms and their neighbors are directed towards the corners of a ~~regular tetrahedron~~. ~~This led~~ to ~~a better understanding of the three-dimensional nature of molecules.~~

	~~== Theory ==~~

	~~Optical activity is a type of [[birefringence]]. Any linear polarization of light can be written as an equal combination of right-hand (RHC) and left-hand circularly (LHC) polarized light~~:
	:~~<math>\mathbf{E}_{\theta_0}=\mathbf{E}_{RHC}+e^{i2\theta_0}\mathbf{E}_{LHC},<~~/~~math>~~
	~~where <math>\mathbf{E}<~~/~~math> is the [[electric field]] of the light~~. ~~The relative phase between the two [[circular polarization]]s, <math>2\theta_0</math>, sets the direction of the linear polarization to <math>\theta_0<~~/~~math>. In an optically active material, the two circular polarizations experience different [[refractive~~ index~~\|refractive indices]]~~. ~~The difference in the indices quantifies the strength of the optical activity,~~
	~~:<math>\Delta n~~=~~n_{RHC}-n_{LHC} \,</math>.~~
	This difference is a characteristic of the material (for substances in solution, it is given as the [[specific rotation]]). After traveling through length <math>L</math> of material, the two polarizations pick up a relative phase of
	:<~~math>2\Delta \theta=\frac{\Delta n L2\pi}{\lambda}</math>,~~
	~~where <math~~>~~\lambda~~<~~/math~~> ~~is the wavelength of the light (in vacuum). As a consequence, the final polarization is rotated~~ to ~~angle <math>\theta_0+\Delta \theta</math>.~~

	In general, the refractive index depends on the wavelength (see [[Dispersion (optics)\|dispersion]]). The variation in rotation with the wavelength of the light is called [[optical rotatory dispersion]] (ORD). ORD spectra and [[circular dichroism]] spectra are related through the [[Kramers–Kronig relation]]s. Complete knowledge of one spectrum allows the calculation of the other.

	In summary, the degree of rotation depends on the color of the light (the yellow sodium D line near 589 nm [[wavelength]] is commonly used for measurements), the path length <math>L</math> and the properties of the material (e.g., <math>\Delta n</math> or [[specific rotation]] and concentration).

	~~== Molecular optical activity and the rotation of plane polarized light ==~~

	The ability to rotate [[Linear polarization\|plane]] [[polarized light]] is a property possessed by every single (individual) molecule. That is to say, each individual molecule of any given compound is optically active.

	When a beam of plane polarized light encounters an ''individual'' molecule, (for example, in a liquid sample of a non-chiral compound), in almost all cases its plane is rotated by a certain amount due to its interaction with the charged particles of the molecule. For a given compound, the extent and direction of this rotation depends on the orientation of the molecule in relation to the beam.

	Because of the very large number and random distribution of the molecules that comprise even the smallest sample, each of these individual rotations is, in effect, canceled out due to the presence of an ''identical molecule that is orientated as the exact geometric mirror image of another'' within the sample. The combined result of all of these cancellations is no net rotation of the plane polarized light and thus optical inactivity.

	Optical inactivity is therefore not a property of individual molecules but a bulk property resulting from the random distribution of molecules within a sample, which can serve as geometric mirror images of each other.

	~~For compounds that exhibit [[Chirality (chemistry)\|chirality]] ([[enantiomers]]) this same cancellation effect is responsible for the optical inactivity of a [[racemic mixture]].~~
	However, for a sample of a pure enantiomer or one that is [[enantiomeric excess \|enantiomerically enriched]], this phenomena of exact cancellation of individual rotations can not occur and therefore the result is optical activity.

	~~== Areas of use ==~~

	~~[[Image~~:~~Sucrose solution and polaroid (optical activity).jpg\|200px\|thumb\|Sucrose solution concentration measuring experiment, demonstrating optical rotation.]]~~

	For a pure substance in solution, if the color and path length are fixed and the [[specific rotation]] is known, the observed rotation can be used to calculate the concentration. This usage makes a [[Polarimetry\|polarimeter]] a tool of great importance to those trading in or using sugar syrups in bulk.

	In the presence of an applied [[magnetic field]], it is possible for samples of all compounds to exhibit optical activity. A magnetic field aligned in the direction of light propagating through a material will cause the rotation of the plane of linear polarization. This [[Faraday effect]] is one of the first discoveries of the relationship between light and electromagnetic effects.

	Optical activity or rotation should not be confused with [[circularly polarized light]]. Circularly polarized light is often presented as a linear polarization rotating as the light propagates. However, in this picture, the polarization completely rotates in a length equal to the wavelength (roughly one micrometer for visible light), and it can happen in vacuum. In contrast, optical activity occurs only in a material, and a complete rotation occurs in a length of millimeters to meters, depending on the material.

	~~== References ==~~
	* Eugene Hecht, ''Optics'', 3rd Ed., Addison-Wesley, 1998, ISBN 0-201-30425-2

	* [[Akhlesh Lakhtakia]], [http://~~ebooks.worldscinet.com/ISBN/9789812812100/toc.shtml Beltrami Fields in Chiral Media], World Scientific, Singapore, 1994~~

	* A step by step tutorial on [https://perswww.kuleuven.be/~~~u0052493/English/RechercheT2a.htm Optical Rotation]~~

	* Morrison. Robert. T, and Boyd. Robert. N, "Organic Chemistry (6th ed)". Prentice-Hall Inc (1992).

	~~== See also =~~=
	* [[Cryptochirality]]
	* [[Specific rotation]]
	* [[Circular dichroism]]
	* [[Birefringence]]
	* [[Polarization (waves)\|Polarization]]
	* [[Levorotation and dextrorotation]]
	* [[Chirality (chemistry)]]
	* [[Polarization rotator]]

	~~{{Chiral synthesis}}~~

	~~[[Category~~:~~Polarization (waves)]]~~
	~~[[Category:Stereochemistry]~~]

en>Bgwhite: Reverted edits by 168.69.134.253 (talk) to last version by 178.41.35.236

2014-01-14T05:57:33Z

Reverted edits by 168.69.134.253 (talk) to last version by 178.41.35.236

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en>Nasnema: Reverted edits by 121.79.195.20 (talk) to last revision by ClueBot NG (HG)

2012-08-01T23:51:38Z

Reverted edits by 121.79.195.20 (talk) to last revision by ClueBot NG (HG)

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== 2、しかし甘いNalanのレートで唯一10メートル、間の ==

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Right triangle - Revision history

en>ClueBot NG: Reverting possible vandalism by 164.116.245.215 to version by Mimarx. False positive? Report it. Thanks, ClueBot NG. (2047020) (Bot)

en>Epicgenius: Reverted 2 edits by 107.204.21.216 identified as test/vandalism using STiki (Mistake? Report it.)

en>Bgwhite: Reverted edits by 168.69.134.253 (talk) to last version by 178.41.35.236

en>Nasnema: Reverted edits by 121.79.195.20 (talk) to last revision by ClueBot NG (HG)