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{{for|the mass spectrometry technique|time-of-flight mass spectrometry}}
'''Time of flight''' (TOF) describes a variety of methods that measure the time that it takes for an object, particle or acoustic, electromagnetic or other wave to travel a distance through a medium. This measurement can be used for a time standard (such as an atomic fountain), as a way to measure velocity or path length through a given medium, or as a way to learn about the particle or medium (such as composition or flow rate). The traveling object may be detected directly (e.g., ion detector in mass spectrometry) or indirectly (e.g., light scattered from an object in laser doppler velocimetry).
 
* In [[electronics]], the TOF method is used to estimate the [[electron mobility]]. Originally, it was designed for measurement of low-conductive thin films, later adjusted for common semiconductors. This experimental technique is used for metal-dielectric-metal structures <ref>{{cite journal|author=R.G. Kepler|journal=Phys. Rev.|volume= 119|year=1960|page=1226|doi=10.1103/PhysRev.119.1226|bibcode = 1960PhRv..119.1226K|title=Charge Carrier Production and Mobility in Anthracene Crystals|issue=4 }}</ref> as well as organic field-effect transitors.<ref>{{cite journal|author=M. Weis, J. Lin, D. Taguchi, T. Manaka, M. Iwamot|journal=J. Phys. Chem. C|volume= 113|year=2009|page=18459|doi=10.1021/jp908381b|title=Analysis of Transient Currents in Organic Field Effect Transistor: The Time-of-Flight Method|issue=43}}</ref> The excess charges are generated by application of the laser or voltage pulse.
 
* In [[time-of-flight mass spectrometry]], ions are accelerated by an electrical field to the same [[kinetic energy]] with the velocity of the ion depending on the [[mass-to-charge ratio]]. Thus the time-of-flight is used to measure velocity, from which the mass-to-charge ratio can be determined.<ref>{{cite book |author=Cotter, Robert J. |title=Time-of-flight mass spectrometry |publisher=American Chemical Society |location=Columbus, OH |year=1994 |pages= |isbn=0-8412-3474-4 |oclc= |doi=}}</ref> The time-of-flight of [[electron]]s is used to measure their kinetic energy.<ref>[http://www.osti.gov/bridge/servlets/purl/764241-IyAfiC/webviewable/764241.pdf Time-of-Flight Techniques For The Investigation Of Kinetic Energy Distributions Of Ions And Neutrals Desorbed By Core Excitations]</ref>
 
* In [[near infrared spectroscopy]], the TOF method is used to measure the media-dependent optical pathlength over a range of optical wavelengths, from which composition and properties of the media can be analyzed.
 
* In [[ultrasonic flow meter]] measurement, TOF is used to measure speed of signal propagation upstream and downstream of flow of a media, in order to estimate total flow velocity. This measurement is made in a collinear direction with the flow.
 
* In [[planar Doppler velocimetry]] (optical flow meter measurement), TOF measurements are made perpendicular to the flow by timing when individual particles cross two or more locations along the flow (collinear measurements would require generally high flow velocities and extremely narrow-band optical filters).
 
* In optical interferometry, the pathlength difference between sample and reference arms can be measured by TOF methods, such as frequency modulation followed by phase shift measurement or cross correlation of signals. Such methods are used in laser radar and laser tracker systems for medium-long range distance measurement.
 
* In [[kinematics]], TOF is the duration in which a projectile is traveling through the air. Given the initial velocity <math>u</math> of a particle launched from the ground, the downward (i.e. gravitational) acceleration <math>a</math>, and the projectile's angle of projection θ (measured relative to the horizontal), then a simple rearrangement of the [[SUVAT equations|SUVAT equation]]
 
:<math>s = vt - \begin{matrix} \frac{1}{2} \end{matrix} at^2</math>
 
results in this equation
 
:<math>t=\frac {2v \sin \theta} {a}</math>
 
for the time of flight of a projectile.
 
== Time-of-flight mass spectrometry ==
[[File:LCMS-IT-TOF.jpg|thumb|Shimadzu Ion Trap TOF|Shimadzu Ion Trap TOF]] {{main|Time-of-flight mass spectrometry}}
[[Time-of-flight mass spectrometry]] (TOFMS) is a method of [[mass spectrometry]] in which [[ion]]s are accelerated by an [[electric field]] of known strength. This acceleration results in an ion having the same [[kinetic energy]] as any other ion that has the same charge. The velocity of the ion depends on the [[mass-to-charge ratio]]. The time that it subsequently takes for the particle to reach a detector at a known distance is measured.  This time will depend on the [[mass-to-charge ratio]] of the particle (heavier particles reach lower speeds).  From this time and the known experimental parameters one can find the [[mass-to-charge ratio]] of the ion. The elapsed time from the instant a particle leaves a source to the instant it reaches a detector.
 
== Ultrasonic and optical time-of-flight flow meters ==
An [[ultrasonic flow meter]] measures the velocity of a liquid or gas through a pipe using acoustic sensors.  This has some advantages over other measurement techniques. The results are slightly affected by temperature, density or conductivity.  Maintenance is inexpensive because there are no [[moving parts]].
 
Ultrasonic flow meters come in three different types: transmission (contrapropagating transit time) flowmeters, reflection (Doppler) flowmeters, and open-channel flowmeters. Transit time flowmeters work by measuring the time difference between an ultrasonic pulse sent in the flow direction and an ultrasound pulse sent opposite the flow direction. Doppler flowmeters measure the [[doppler shift]] resulting in reflecting an ultrasonic beam off either small particles in the fluid, air bubbles in the fluid, or the flowing fluid's turbulence. Open channel flow meters measure upstream levels in front of [[flume]]s or [[weir]]s.
 
Optical time-of-flight sensors consist of two light beams projected into the fluid whose detection is either interrupted or instigated by the passage of small particles (which are assumed to be following the flow). This is not dissimilar from the optical beams used as safety devices in motorized garage doors or as triggers in alarm systems. The speed of the particles is calculated by knowing the spacing between the two beams. If there is only one detector, then the time difference can be measured via [[autocorrelation]]. If there are two detectors, one for each beam, then direction can also be known. Since the location of the beams is relatively easy to determine, the precision of the measurement depends primarily on how small the setup can be made. If the beams are too far apart, the flow could change substantially between them, thus the measurement becomes an average over that space. Moreover, multiple particles could reside between them at any given time, and this would corrupt the signal since the particles are indistinguishable. For such a sensor to provide valid data, it must be small relative to the scale of the flow and the seeding density. [[MOEMS]] approaches yield extremely small packages, making such sensors applicable in a variety of situations.<ref>{{Cite journal | last1  = Modarress|first1 = D. | last2 = Svitek | first2 = P. | last3 = Modarress | first3 = K. | last4 = Wilson | first4 = D. | title = Micro-optical sensors for boundary layer flow studies | journal = 2006 ASME Joint U.S.-European Fluids Engineering Summer Meeting |date=July 2006 | url = http://www.measurementsci.com/papers/FEDSM06_98556.pdf}}</ref>
 
== High-precision measurements in physics ==
Usually the tube is praised for simplicity, but for precision measurements of charged low energy particles the electric and the magnetic field in the flight tube has to be controlled within 10 mV and 1 nT respectively.
 
The [[work function]] homogeneity of the tube can be controlled by a [[Kelvin probe force microscope|Kelvin probe]]. The magnetic field can be measured by a [[fluxgate compass]]. High frequencies are passively shielded and damped by [[radar absorbent material]]. To generate arbitrary low frequencies field the screen is parted into plates (overlapping and connected by capacitors) with bias voltage on each plate and a bias current on coil behind plate whose flux is closed by an outer core. In this way the tube can be configured to act as a weak achromatic quadrupole lens with an aperture with a grid and a delay line detector in the diffraction plane to do angle resolved measurements. Changing the field the angle of the field of view can be changed and a deflecting bias can be superimposed to scan through all angles.
 
When no delay line detector is used focusing the ions onto a detector can be accomplished through the use of two or three [[einzel lens]]es placed in the vacuum tube located between the ion source and the detector.
 
The sample should be immersed into the tube with holes and apertures for and against stray light to do magnetic experiments and to control the electrons from their start.
 
==See also==
* [[Time-of-flight camera]]
* [[Travel time]]
* [[Time of arrival]]
 
== References ==
<references/>
 
{{DEFAULTSORT:Time-Of-Flight}}
[[Category:Mass spectrometry]]
[[Category:Spectroscopy]]

Revision as of 03:35, 13 January 2014

28 year-old Painting Investments Worker Truman from Regina, usually spends time with pastimes for instance interior design, property developers in new launch ec Singapore and writing. Last month just traveled to City of the Renaissance. Time of flight (TOF) describes a variety of methods that measure the time that it takes for an object, particle or acoustic, electromagnetic or other wave to travel a distance through a medium. This measurement can be used for a time standard (such as an atomic fountain), as a way to measure velocity or path length through a given medium, or as a way to learn about the particle or medium (such as composition or flow rate). The traveling object may be detected directly (e.g., ion detector in mass spectrometry) or indirectly (e.g., light scattered from an object in laser doppler velocimetry).

  • In electronics, the TOF method is used to estimate the electron mobility. Originally, it was designed for measurement of low-conductive thin films, later adjusted for common semiconductors. This experimental technique is used for metal-dielectric-metal structures [1] as well as organic field-effect transitors.[2] The excess charges are generated by application of the laser or voltage pulse.
  • In near infrared spectroscopy, the TOF method is used to measure the media-dependent optical pathlength over a range of optical wavelengths, from which composition and properties of the media can be analyzed.
  • In ultrasonic flow meter measurement, TOF is used to measure speed of signal propagation upstream and downstream of flow of a media, in order to estimate total flow velocity. This measurement is made in a collinear direction with the flow.
  • In planar Doppler velocimetry (optical flow meter measurement), TOF measurements are made perpendicular to the flow by timing when individual particles cross two or more locations along the flow (collinear measurements would require generally high flow velocities and extremely narrow-band optical filters).
  • In optical interferometry, the pathlength difference between sample and reference arms can be measured by TOF methods, such as frequency modulation followed by phase shift measurement or cross correlation of signals. Such methods are used in laser radar and laser tracker systems for medium-long range distance measurement.
  • In kinematics, TOF is the duration in which a projectile is traveling through the air. Given the initial velocity of a particle launched from the ground, the downward (i.e. gravitational) acceleration , and the projectile's angle of projection θ (measured relative to the horizontal), then a simple rearrangement of the SUVAT equation

results in this equation

for the time of flight of a projectile.

Time-of-flight mass spectrometry

Shimadzu Ion Trap TOF

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church.

Time-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which ions are accelerated by an electric field of known strength. This acceleration results in an ion having the same kinetic energy as any other ion that has the same charge. The velocity of the ion depends on the mass-to-charge ratio. The time that it subsequently takes for the particle to reach a detector at a known distance is measured. This time will depend on the mass-to-charge ratio of the particle (heavier particles reach lower speeds). From this time and the known experimental parameters one can find the mass-to-charge ratio of the ion. The elapsed time from the instant a particle leaves a source to the instant it reaches a detector.

Ultrasonic and optical time-of-flight flow meters

An ultrasonic flow meter measures the velocity of a liquid or gas through a pipe using acoustic sensors. This has some advantages over other measurement techniques. The results are slightly affected by temperature, density or conductivity. Maintenance is inexpensive because there are no moving parts.

Ultrasonic flow meters come in three different types: transmission (contrapropagating transit time) flowmeters, reflection (Doppler) flowmeters, and open-channel flowmeters. Transit time flowmeters work by measuring the time difference between an ultrasonic pulse sent in the flow direction and an ultrasound pulse sent opposite the flow direction. Doppler flowmeters measure the doppler shift resulting in reflecting an ultrasonic beam off either small particles in the fluid, air bubbles in the fluid, or the flowing fluid's turbulence. Open channel flow meters measure upstream levels in front of flumes or weirs.

Optical time-of-flight sensors consist of two light beams projected into the fluid whose detection is either interrupted or instigated by the passage of small particles (which are assumed to be following the flow). This is not dissimilar from the optical beams used as safety devices in motorized garage doors or as triggers in alarm systems. The speed of the particles is calculated by knowing the spacing between the two beams. If there is only one detector, then the time difference can be measured via autocorrelation. If there are two detectors, one for each beam, then direction can also be known. Since the location of the beams is relatively easy to determine, the precision of the measurement depends primarily on how small the setup can be made. If the beams are too far apart, the flow could change substantially between them, thus the measurement becomes an average over that space. Moreover, multiple particles could reside between them at any given time, and this would corrupt the signal since the particles are indistinguishable. For such a sensor to provide valid data, it must be small relative to the scale of the flow and the seeding density. MOEMS approaches yield extremely small packages, making such sensors applicable in a variety of situations.[5]

High-precision measurements in physics

Usually the tube is praised for simplicity, but for precision measurements of charged low energy particles the electric and the magnetic field in the flight tube has to be controlled within 10 mV and 1 nT respectively.

The work function homogeneity of the tube can be controlled by a Kelvin probe. The magnetic field can be measured by a fluxgate compass. High frequencies are passively shielded and damped by radar absorbent material. To generate arbitrary low frequencies field the screen is parted into plates (overlapping and connected by capacitors) with bias voltage on each plate and a bias current on coil behind plate whose flux is closed by an outer core. In this way the tube can be configured to act as a weak achromatic quadrupole lens with an aperture with a grid and a delay line detector in the diffraction plane to do angle resolved measurements. Changing the field the angle of the field of view can be changed and a deflecting bias can be superimposed to scan through all angles.

When no delay line detector is used focusing the ions onto a detector can be accomplished through the use of two or three einzel lenses placed in the vacuum tube located between the ion source and the detector.

The sample should be immersed into the tube with holes and apertures for and against stray light to do magnetic experiments and to control the electrons from their start.

See also

References

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    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

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    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

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    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

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  4. Time-of-Flight Techniques For The Investigation Of Kinetic Energy Distributions Of Ions And Neutrals Desorbed By Core Excitations
  5. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

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    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

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    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang