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[[File:Bouteille air démarrage.JPG|thumb|250px|A pressurized air tank used to start a diesel generator set in Paris Metro]]
'''Compressed air energy storage''' ('''CAES''') is a way to [[energy storage|store energy]] generated at one time for use at another time. At utility scale, energy generated during periods of low energy demand (off-peak) can be released to meet higher demand ([[peak load]]) periods.<ref name="NYT-2010.07.28">Wild, Matthew, L. [http://www.nytimes.com/2010/07/28/business/energy-environment/28storage.html Wind Drives Growing Use of Batteries], [[New York Times]], July 28, 2010, pp.B1.</ref>
 
== Types ==
 
[[Gas compressor|Compression]] of [[air]] generates heat; the air is warmer after compression. [[Thermal expansion|Expansion]] requires heat. If no extra heat is added, the air will be much colder after expansion. If the heat generated during compression can be stored and used during expansion, the efficiency of the storage improves considerably.<ref name="NYTimes-2012.10.01">Gies, Erica. [http://www.nytimes.com/2012/10/02/business/energy-environment/a-storage-solution-is-in-the-air.html?pagewanted=all Global Clean Energy: A Storage Solution Is in the Air], ''[[International Herald Tribune]]'', October 1, 2012. Retrieved from NYTimes.com website, March 19, 2013.</ref> There are three ways in which a CAES system can deal with the heat. Air storage can be [[adiabatic]], [[diabatic]], or [[isothermal]].
 
===Adiabatic===
Adiabatic storage retains the heat produced by compression and returns it to the air when the air is expanded to generate power. This is a subject of ongoing study, with no utility scale plants as of 2010, but a German project ADELE is planned to enter development in 2013.<ref name="ADELE1">{{cite web| title = ADELE – Adiabatic compressed-air energy storage (CAES) for electricity supply| url = http://www.rwe.com/web/cms/en/365478/rwe/innovations/power-generation/energy-storage/compressed-air-energy-storage/project-adele/| accessdate = December 31, 2011}}</ref> The theoretical [[Energy conversion efficiency|efficiency]] of adiabatic storage approaches 100% with perfect insulation, but in practice round trip efficiency is expected to be 70%.<ref name="BINE1">{{cite web| title = German AACAES project information| url = http://www.bine.info/pdf/publikation/projekt0507englinternetx.pdf| accessdate = February 22, 2008}}</ref> Heat can be stored in a solid such as concrete or stone, or more likely in a fluid such as hot oil (up to 300&nbsp;°C) or molten salt solutions (600&nbsp;°C).
 
===Diabatic===
Diabatic storage dissipates much of the heat of compression with [[intercooler]]s (thus approaching isothermal compression) into the atmosphere as waste; essentially wasting, thereby, the renewable energy used to perform the work of compression.  Upon removal from storage, the temperature of this compressed air is ''the one indicator'' of the amount of stored energy that remains in this air. Consequently, if the air temperature is low for the energy recovery process, the air must be substantially re-heated prior to expansion in the [[turbine]] to power a [[Electrical generator|generator]]. This reheating can be accomplished with a natural gas fired burner for [[utility]] grade storage or with a heated metal mass. As recovery is often most needed when renewable sources are quiescent, fuel must be burned to make up for the ''wasted'' heat.  This degrades the efficiency of the storage-recovery cycle; and while this approach is relatively simple, the burning of fuel adds to the cost of the recovered electrical energy and compromises the ecological benefits associated with most renewable energy sources.  Nevertheless, this is thus far the only system which has been implemented commercially.
 
The [[Energy storage#Mechanical storage|McIntosh, Alabama CAES plant]] requires 2.5 MJ of electricity and 1.2 MJ [[lower heating value]] (LHV) of gas for each megajoule of energy output, corresponding to an energy recovery efficiency of about 27%.<ref>
http://my.epri.com/portal/server.pt?Abstract_id=TR-101751-V2</ref> A [[General Electric]] 7FA 2x1 [[combined cycle]] plant, one of the most efficient natural gas plants in operation, uses 6.6 MJ (LHV) of gas per kW·h generated,<ref>http://www.westgov.org/wieb/electric/Transmission%20Protocol/SSG-WI/pnw_5pp_02.pdf</ref> a 54% thermal efficiency compared to the McIntosh 6.8 MJ, at 27% thermal efficiency.
 
===Isothermal===
Isothermal compression and expansion approaches attempt to maintain [[operating temperature]] by constant heat exchange to the environment. They are only practical for low power levels, without very effective [[heat exchanger]]s. The theoretical efficiency of isothermal energy storage approaches 100% for perfect heat transfer to the environment. In practice neither of these perfect thermodynamic cycles are obtainable, as some heat losses are unavoidable.
 
===Other===
One implementation of isothermal CAES, uses high, medium and low pressure pistons in series, with each stage followed by an airblast [[venturi pump]] that draws ambient air over an air-to-air (or air-to-seawater) heat exchanger between each expansion stage. Early [[Torpedo#Compressed air|compressed air torpedo]] designs used a similar approach, substituting seawater for air. The venturi warms the [[exhaust gas|exhaust]] of the preceding stage and admits this preheated air to the following stage. This approach was widely adopted in various compressed air vehicles such as [[H. K. Porter, Inc]]'s mining [[locomotives]]<ref>
[http://www.aqpl43.dsl.pipex.com/MUSEUM/TRANSPORT/comprair/comprair.htm Compressed-Air Propulsion<!-- Bot generated title -->]</ref> and trams.<ref name=autogenerated1>
[http://www.aircaraccess.com/images/3stage%201.jpg 3-stage propulsion with intermediate heating]</ref> Here the heat of compression is effectively stored in the atmosphere (or sea) and returned later on.
 
==Compressors and expanders==
Compression can be done with electrically powered [[turbocompressor|turbo-compressor]]s and expansion with turbo 'expanders'<ref name="DEP1">{{cite web|title=Distributed Energy Program: Compressed Air Energy Storage|url=http://www.eere.energy.gov/de/compressed_air.html|publisher=United States Department of Energy|accessdate=August 27, 2006}}</ref> or [[air engine]]s driving [[electrical generator]]s to produce electricity.
 
==Storage==
The storage vessel is often an underground cavern created by [[solution mining]] (salt is dissolved in water for extraction)<ref>http://www.answers.com/topic/solution-mining?cat=technology ; http://www.saltinstitute.org/12.html</ref> or by utilizing an abandoned [[mining|mine]]; use of porous rock formations such as those in which reservoirs of natural gas are found has also been studied.<ref name=PNNL413>{{cite web|title=Compressed Air Energy Storage|url=http://caes.pnnl.gov/|publisher=Pacific Northwest National Laboratory|accessdate=May 20, 2013|date=April 2013}}</ref> Plants operate on a daily cycle, charging at night and discharging during the day. Heating of the compressed air using natural gas or geothermal heat to increase the amount of energy being extracted has been studied by the [[Pacific Northwest National Laboratory]]<ref name=PNNL413 />
 
Compressed air energy storage can also be employed on a smaller scale such as exploited by [[air car]]s and air-driven [[locomotive]]s, and also by the use of high-strength [[carbon-fiber]] air storage tanks. However, when compressed air is stored at ''room temperature'' this stored air, in general, contains the same amount of energy per pound as uncompressed room temperature air. The considerable amount of energy used to compress this air '''''is not stored there''''' if the air is allowed to reduce to room temperature. Therefore, to obtain substantial energy from the expansion of this stored room temperature compressed air a heat reservoir must be provided to supply the needed energy. This can be challenging in mobile applications.
 
==Specialized applications==
{{Patent|US|8347628|''Power generation directly from compressed air for exploiting wind and solar power''}}, awarded in January 2013, describes a turbo-expander machine that offers both high efficiency energy recovery and high power output.
The turbo-expander utilizes no fuel combustion, but instead is powered by the recovery of atmospheric heat (e.g., the ''wasted'' heat of compression as described in the Diabatic classification).
When combined with renewable energy powered air compression, such an energy recovery machine would enable a compressed air ''storage and recovery'' methodology that is both cost-effective and eco-friendly.
 
== History ==
 
City-wide compressed air energy systems have been built since 1870.<ref name=chambers>
 
{{cite book
  | title = Chambers's Encyclopaedia: A Dictionary of Universal Knowledge
  | year = 1896
  | publisher=W. & R. Chambers, LTD
  | pages = 252–253
  | url = http://books.google.com/books?id=4pwMAAAAYAAJ&pg=PA252
  | accessdate = January 7, 2009}}
 
</ref> Cities such as [[Paris, France]]; [[Birmingham, England]]; [[Dresden, Germany|Dresden]], [[Rixdorf]] and [[Offenbach, Germany]] and [[Buenos Aires, Argentina]] installed such systems. [[Victor Popp]] constructed the first systems to power clocks by sending a pulse of air every minute to change their pointer arms. They quickly evolved to deliver power to homes and industry.<ref>Technische Mislukkingen by Lex Veldhoen & Jan van den Ende</ref> As of 1896, the Paris system had 2.2 MW of generation distributed at 550 kPa in 50&nbsp;km of air pipes for motors in light and heavy industry.  Usage was measured by meters.<ref name=chambers/>  The systems were the main source of house-delivered energy in these days and also powered the machines of [[dentistry|dentists]], [[seamstress]]es, printing facilities and [[bakery|bakeries]].
* 1978 – The first utility-scale compressed air energy storage project was the 290 megawatt Huntorf plant in Germany using a salt dome.
* 1991 – A 110 megawatt plant with a capacity of 26 hours was built in McIntosh, Alabama (1991). The Alabama facility's $65 million cost works out to $550 per Kilowatt hour of capacity, using a 19 million cubic foot [[In-situ leach|solution mined]] salt cavern to store air at up to 1100 psi.  Although the compression phase is approximately 82% efficient, the expansion phase requires combustion of natural gas at one third the rate of a gas turbine producing the same amount of electricity.<ref>{{citation|url=http://www.dresser-rand.com/literature/general/85164-10-CAES.pdf|format=pdf|title=Compressed Air Storage (CAES)|publisher=Dresser-Rand Corporation|id=brochure form# 85230|year=2010}}</ref><ref>{{citation|publisher=New York Times|date=September 29, 1991|last=Wald|first=Matthew|title=Using Compressed Air To Store Up Electricity|url=http://www.nytimes.com/1991/09/29/business/technology-using-compressed-air-to-store-up-electricity.html?pagewanted=all&src=pm}}</ref><ref>{{citation|accessdate=April 15, 2012|year=2010 |publisher=PowerSouth Energy Cooperative|url=http://www.powersouth.com/mcintosh_power_plant/compressed_air_energy|title=CAES:McIntosh Power Plant }}</ref>
*November 2009 – The US Department of energy awards $24.9 million in matching funds for phase one of a 300 MW, $356 million Pacific Gas and Electric CAES installation utilizing a saline porous rock formation being developed near Bakersfield in Kern County, California. Goals of the project is to build and validate an advanced design.<ref name=sandia1>{{citation|url=http://www.sandia.gov/ess/docs/ARRA_StorDemos_4-22-11.pdf|format=pdf|title=ARRA Energy Storage Demonstrations|publisher=Sandia National Laboratories|accessdate=April 13, 2012}}</ref>
*December, 2010 – DOE provides $29.4 million in funding to conduct preliminary work on a 150 MW salt-based CAES project being developed by [[Iberdrola|Iberdrola USA]] in Watkins Glen, New York.  The goal is to incorporate smart grid technology to balance renewable [[intermittent energy source]]s.<ref name=sandia1 /><ref>{{citation| title=NYSEG considering Compressed Air Energy Storage|publisher= Energy Overviews Publishing|accessdate=April 13, 2012|url=http://epoverviews.com/articles/visitor.php?keyword=Smart%20Grid%20Demonstration}}</ref>
* December, 2012 – General Compression completes construction of a 2MW near-isothermal CAES project in Gaines, TX; the world's third CAES project. The project uses no fuel and has 500MWh of storage capacity. <ref>{{cite web|last=General Compression, Inc.|title=What We Do – Texas Dispatachable Wind 1, LLC|url=http://www.generalcompression.com/index.php/tdw1|accessdate=2 March 2013}}</ref>
* 2013 (projected) – The first adiabatic CAES project, a 200 megawatt facility called ADELE, is planned for construction in Germany.
* 2016 (projected) – Apex has planned a CAES plant for [[Anderson County, Texas]] to go online in 2016<ref>{{citation|title=Anderson County getting energy center|accessdate=July 15, 2012|url=http://palestineherald.com/local/x941521205/Anderson-County-getting-energy-center}}</ref>
 
== Storage thermodynamics ==
 
In order to achieve a near [[Reversible process (thermodynamics)|thermodynamic reversible process]] so that most of the energy is saved in the system and can be retrieved, and losses are kept negligible, a near reversible [[isothermal process]] or an [[isentropic process]] is desired.<ref name="NYTimes-2012.10.01" />
 
=== Isothermal storage ===
 
In an [[isothermal process|isothermal]] compression process, the gas in the system is kept at a constant temperature throughout. This necessarily requires removal of heat from the gas, which otherwise would experience a temperature rise due to the energy that has been added to the gas by the compressor. This heat removal can be achieved by heat exchangers (intercooling) between subsequent stages in the compressor. To avoid wasted energy, the intercoolers must be optimised for high [[heat transfer]] and low pressure drop. Naturally this is only an approximation to an isothermal compression, since the heating and compression occurs in discrete phases. Some smaller compressors can approximate isothermal compression even without intercooling, due to the relatively high ratio of surface area to volume of the compression chamber and the resulting improvement in heat dissipation from the compressor body itself.
 
To obtain a perfect isothermal storage process, the process must be reversible. This requires that the heat transfer between the surroundings and the gas occur over an infinitesimally small temperature difference. In that case, there is no [[exergy]] loss in the heat transfer process, and so the compression work can be completely recovered as expansion work: 100% storage efficiency. However, in practice, there is always a temperature difference in any heat transfer process, and so all practical energy storage obtains efficiencies significantly lower than 100%.
 
To estimate the compression/expansion work in an isothermal process, it may be assumed that the compressed air obeys the [[ideal gas law]],
:<math>pV=nRT=\operatorname{constant}</math>.
From a process from an initial state ''A'' to a final state ''B'', with [[absolute temperature]] <math>T = T_A = T_B</math> constant, one finds the work required for compression (negative) or done by the expansion (positive), to be
:<math>\begin{align}
W_{A\to B} & = \int_{V_A}^{V_B} p dV = \int_{V_A}^{V_B} \frac{nRT}{V} dV = nRT\int_{V_A}^{V_B} \frac{1}{V} dV \\
& = nRT(\ln{V_B}-\ln{V_A}) = nRT\ln{\frac{V_B}{V_A}} = nRT\ln{\frac{p_A}{p_B}} = p_A V_A\ln{\frac{p_A}{p_B}} \\
\end{align}</math>,
where <math>pV = p_A V_A = p_B V_B</math>, and so, <math>\frac{V_B}{V_A} = \frac{p_A}{p_B} </math>. Here, <math>p</math> is the absolute [[pressure]],
<math>V</math> is the [[volume]] of the vessel, <math>n</math> is the [[amount of substance]] of gas (mol) and <math>R</math> is the [[ideal gas constant]].
 
''Example''
 
How much energy can be stored in a 1 m³ storage vessel at a pressure of 70 bar (7.0 MPa), if the ambient pressure is 1 bar (0.1 MPa). In this case, the process work is
 
:<math>W = p_B v_B \ln \frac{p_A}{p_B}</math> = 7.0 MPa × 1 m³ × ln(0.1 MPa / 7.0 MPa) = -29.7 MJ.
 
The negative sign means that work is done on the gas by the surroundings. Process irreversibilities (such as in heat transfer) will result in less energy being recovered from the expansion process than is required for the compression process. If the environment is at a constant temperature, for example, the thermal resistance in the intercoolers will mean that the compression occurs at a temperature somewhat higher than the ambient temperature, and the expansion will occur at a temperature somewhat lower than ambient temperature. So a perfect isothermal storage system is impossible to achieve.
 
=== Adiabatic (isentropic) storage ===
 
An [[adiabatic process]] is one where there is no heat transfer between the fluid and the surroundings: the system is insulated against heat transfer. If the process is furthermore internally reversible (smooth, slow and frictionless, to the ideal limit) then it will additionally be [[isentropic]].
 
An adiabatic storage system does away with the intercooling during the compression process, and simply allows the gas to heat up during compression, and likewise to cool down during expansion. This is attractive, since the energy losses associated with the heat transfer are avoided, but the downside is that the storage vessel must be insulated against heat loss. It should also be mentioned that real compressors and turbines are not isentropic, but instead have an [[Steam_turbine#Isentropic_turbine_efficiency|isentropic efficiency]] of around 85%, with the result that round-trip storage efficiency for adiabatic systems is also considerably less than perfect.
 
=== Large storage system thermodynamics ===
 
Energy storage systems often use large underground caverns. This is the preferred system design, due to the very large volume, and thus the large quantity of energy that can be stored with only a small pressure change. The cavern space can be easily insulated, compressed adiabatically with little temperature change (approaching a reversible isothermal system) and heat loss (approaching an isentropic system). This advantage is in addition to the low cost of constructing the gas storage system, using the underground walls to assist in containing the pressure.
 
Recently there have been developed undersea insulated air bags, with similar thermodynamic properties to large underground cavern storage.<ref>[http://cleantechnica.com/2011/04/18/energy-bags-under-the-sea-to-be-tested-to-store-off-shore-wind/ Energy bags under the sea to be tested] in 2011(Cleantechnica website). See in sections below.</ref>
 
== Practical constraints in transportation ==
 
In order to use air storage in vehicles or aircraft for practical land or air transportation, the energy storage system must be compact and lightweight. [[Energy density]] is the engineering term that defines these desired qualities.
 
=== Energy density and efficiency ===
 
As explained in the thermodynamics of gas storage section above, compressing air heats it and expanding it cools it. Therefore practical air engines require heat exchangers in order to avoid excessively high or low temperatures and even so don't reach ideal constant temperature conditions, or ideal thermal insulation.
 
Nevertheless, as stated above, it is useful to describe the maximum energy storable using the isothermal case, which works out to about 100 kJ/m<sup>3</sup> [&nbsp;ln(''P''<sub>''A''</sub>/''P''<sub>''B''</sub>)].
 
Thus if 1.0&nbsp;m<sup>3</sup> of ambient air is very slowly compressed into a 5 L bottle at 20 MPa (200 bar), the potential energy stored is 530 kJ. A highly efficient air motor can transfer this into kinetic energy if it runs very slowly and manages to expand the air from its initial 20 MPa pressure down to 100 kPa (bottle completely "empty" at ambient pressure).  Achieving high efficiency is a technical challenge both due to heat loss to the ambient and to unrecoverable internal gas heat.<ref>Heat loss of practical systems is explained in the [[#Thermodynamics of heat storage]] section.</ref> If the bottle above is emptied to 1 MPa, the extractable energy is about 300 kJ at the motor shaft.
 
A standard 20 MPa, 5 L steel bottle has a mass of 7.5&nbsp;kg, a superior one 5&nbsp;kg. High-tensile strength fibers such as  [[carbon-fiber]] or [[Kevlar]] can weigh below 2&nbsp;kg in this size, consistent with the legal safety codes. One cubic meter of air at 20 °C has a mass of 1.204&nbsp;kg at [[standard temperature and pressure]].<ref>
[http://www.engineeringtoolbox.com/air-desity-specific-weight-d_600.html Air – Density and Specific Weight], The Engineering Toolbox</ref> Thus, '''''theoretical''''' energy densities are from roughly 70&nbsp;kJ/kg at the motor shaft for a plain steel bottle to 180&nbsp;kJ/kg for an advanced fiber-wound one, whereas practical '''''achievable''''' energy densities for the same containers would be from 40 to 100&nbsp;kJ/kg.
 
=== Comparison with batteries ===
 
Advanced fiber-reinforced bottles are comparable to the [[Rechargeable battery|rechargeable]] [[lead-acid battery]] in terms of energy density. Batteries provide nearly constant voltage over their entire charge level, whereas the pressure varies greatly while using a pressure vessel from full to empty.  It is technically challenging to design air engines to maintain high efficiency and sufficient power over a wide range of pressures. Compressed air can transfer power at very high flux rates, which meets the principal acceleration and deceleration objectives of transportation systems, particularly for [[hybrid vehicles]].
 
Compressed air systems have advantages over conventional batteries including longer lifetimes of [[pressure vessel]]s and lower material toxicity. Newer battery designs such as those based on [[Lithium iron phosphate battery|Lithium Iron Phosphate]] chemistry suffer from neither of these problems. Compressed air costs are potentially lower; however advanced pressure vessels are costly to develop and safety-test and at present are more expensive than mass-produced batteries.
 
As with electric storage technology, compressed air is only as "clean" as the source of the energy that it stores. [[Life cycle assessment]] addresses the question of overall emissions from a given energy storage technology combined with a given mix of generation on a power grid.
 
=== Safety ===
 
As with most technologies, compressed air has safety concerns, mainly catastrophic tank rupture. Safety codes make this a rare occurrence at the cost of higher weight and additional safety features such as pressure relief valves. Codes may limit the legal working pressure to less than 40% of the rupture pressure for steel bottles ([[safety factor]] of 2.5), and less than 20% for fiber-wound bottles ([[safety factor]] of 5).  Commercial designs adopt the [[ISO 11439]] standard.<ref>[http://www.iso.org/iso/catalogue_detail?csnumber=33298 Gas cylinders – High pressure cylinders for the on-board storage of natural gas as a fuel for automotive vehicles]</ref> High pressure bottles are fairly strong so that they generally do not rupture in vehicle crashes.
 
== Vehicle applications ==
 
{{Main|Compressed air vehicles}}
 
=== History ===
 
Air engines have been used since the 19th century to power [[mining|mine]] [[locomotives]], pumps, drills and trams, via centralized, city-level, distribution. [[Racecar]]s use compressed air to start their [[internal combustion engine]] (ICE), and large [[Diesel engine]]s may have starting [[pneumatic motor]]s.
 
[[Image:Compressed Air Loco.jpg|thumb|right|A compressed air locomotive by [[H. K. Porter, Inc.]], in use at the [[Homestake Mine (South Dakota)|Homestake Mine]] between 1928 and 1961.]]
 
=== Engine ===
{{Main|Compressed air engine}}
 
A compressed air engine uses the expansion of compressed air to drive the pistons of an engine, turn the [[axle]], or to drive a [[turbine]].
 
The following methods can increase efficiency:
 
* A continuous expansion turbine at high efficiency
* Multiple expansion stages
* Use of waste heat, notably in a hybrid [[heat engine]] design
* Use of environmental heat
 
A highly efficient arrangement uses high, medium and low pressure pistons in series, with each stage followed by an airblast venturi that draws ambient air over an air-to-air [[heat exchanger]]. This warms the exhaust of the preceding stage and admits this preheated air to the following stage. The only exhaust gas from each stage is cold air which can be as cold as {{convert|−15|°C|°F}}; the cold air may be used for [[air conditioning]] in a car.<ref name=autogenerated1 />
 
Additional heat can be supplied by burning fuel as in 1904 for Whitehead's torpedoes.<ref>
[http://archive.is/DIiw A History of the Torpedo The Early Days<!-- Bot generated title -->]</ref>  This improves the range and speed available for a given tank volume at the cost of the additional fuel.
 
==== Cars ====
{{Main|Compressed-air vehicle|Compressed air car}}
 
Since about 1990 several companies have claimed to be developing compressed air cars, but none are available. Typically the main claimed advantages are: no roadside pollution, low cost, use of cooking oil for [[lubrication]], and integrated air conditioning.
 
The time required to refill a depleted tank is important for vehicle applications. "Volume transfer" moves pre-compressed air from a stationary tank to the vehicle tank almost instantaneously. Alternatively, a stationary or on-board [[Gas compressor|compressor]] can compress air on demand, possibly requiring several hours.
 
== Types of systems ==
 
=== Hybrid systems ===
[[Brayton cycle]] engines compress and heat air with a fuel suitable for an [[internal combustion engine]]. For example, natural gas or [[biogas]] heat compressed air, and then a conventional [[gas turbine]] engine or the rear portion of a [[jet engine]] expands it to produce work.
 
[[Compressed air engine]]s can recharge an [[Battery (electricity)|electric battery]]. The apparently defunct [[Energine]] promoted its Pne-PHEV or Pneumatic Plug-in Hybrid Electric Vehicle-system){{Citation needed|date=April 2008}}.<ref>
[http://www.energine.com/phev/e_phev_03.php Energine PHEV-system schematic]</ref>
 
==== Existing hybrid systems ====
 
Huntorf, Germany in 1978, and [[McIntosh, Alabama]], U.S. in 1991 commissioned hybrid power plants.<ref name="DEP1"/><ref name='new.scientist.com/vol.195 no.2623 p.&nbsp;45'>{{cite journal
|title=Squeeze the breeze: Want to get more electricity from the wind? The key lies beneath our feet |journal=New Scientist |date=November 17, 2007 |first=Daniel|last=Pendick |volume=195|issue=2623|page=4 |url=http://environment.newscientist.com/channel/earth/mg19526231.700-rocks-could-be-novel-store-for-wind-energy.html |accessdate=November 17, 2007 }}</ref> Both systems use off-peak energy for air compression. The McIntosh plant achieves its 24-hour operating cycle by burning a natural gas/compressed air mix.
 
==== Future hybrid systems ====
 
The Iowa Stored Energy Park (ISEP) will use [[aquifer]] storage rather than cavern storage. The displacement of water in the aquifer results in regulation of the air pressure by the constant hydrostatic pressure of the water. A spokesperson for ISEP claims, "you can optimize your equipment for better efficiency if you have a constant pressure."<ref name="new.scientist.com/vol.195 no.2623 p.&nbsp;45"/> Power output of the McIntosh and Iowa systems is in the range of 2–300 MW.<ref>
[http://www.isepa.com/FAQs.asp Frequently Asked Questions]</ref>
 
Additional facilities are under development in [[Norton, Ohio]]. [[FirstEnergy]], an Akron, Ohio electric utility obtained development rights to the 2,700 MW Norton project in November, 2009.<ref>
http://www.firstenergycorp.com/NewsReleases/2009-11-23%20Norton%20Project.pdf</ref>
 
=== Lake or ocean storage ===
 
Deep water in lakes and the ocean can provide pressure without requiring high-pressure vessels or drilling into salt caverns or aquifers.<ref name='caes.aquifer'>{{cite web
|url=http://www.wapa.gov/es/pubs/ESB/2003/03Aug/esb084.htm |title=Wind plus compressed air equals efficient energy storage in Iowa proposal |accessdate=April 29, 2008 |work=Energy Services Bulletin website |publisher=Western Area Power Administration}}</ref> The air goes into inexpensive, flexible containers such as plastic bags below in deep lakes or off sea coasts with steep drop-offs. Obstacles include the limited number of suitable locations and the need for high-pressure pipelines between the surface and the containers. Since the containers would be very inexpensive, the need for great pressure (and great depth) may not be as important. A key benefit of systems built on this concept is that charge and discharge pressures are a constant function of depth. [[Carnot heat engine|Carnot]] inefficiencies can thereby be reduced in the power plant. Carnot efficiency can be increased by using multiple charge and discharge stages and using inexpensive heat sources and sinks such as cold water from rivers or hot water from [[solar pond]]s. Ideally, the system must be very clever—for example, by cooling air before pumping on summer days. It must be engineered to avoid inefficiency, such as wasteful pressure changes caused by inadequate piping diameter.<ref>
[http://www.google.com/patents?id=uno9AAAAEBAJ&dq=4873828 Prior art]. Oliver Laing et al. Energy storage for off peak electricity. United States Patent No. 4873828.</ref>
 
A nearly [[Isobaric process|isobaric]] solution is possible if the compressed gas is used to drive a hydroelectric system. However, this solution requires large pressure tanks located on land (as well as the underwater air bags). Also, hydrogen gas is the preferred fluid, since other gases suffer from substantial hydrostatic pressures at even relatively modest depths (such as 500 meters).
 
E.ON, one of Europe's leading power and gas companies, has provided €1.4 million (£1.1 million) in funding to develop undersea air storage bags.<ref>
{{cite web
|url=http://www.nottingham.ac.uk/news/pressreleases/2008/june/energybagsandsuperbatteries.aspx
|title=Energy bags and super batteries
|date=June 18, 2008
|publisher=Nottingham University
}}</ref>
<ref>
{{cite web
|url=http://news.bbc.co.uk/1/hi/england/nottinghamshire/7315059.stm
|title=The man making 'wind bags'
|date=March 26, 2008
|publisher=BBC
}}</ref>
Hydrostor in Canada is developing a commercial system of underwater storage "accumulators" for compressed air energy storage, starting at the 1 to 4 MW scale.<ref>{{cite web|url=http://techcrunch.com/2011/07/09/hydrostor-power-storage-under-water|title=How Hydrostor Aims To Change The Power Game By Storing Energy Under Water|date=July 9, 2011|publisher=[[TechCrunch]]}}</ref>
 
== See also ==
{{Portal|Energy}}
 
* [[Alternative fuel]]
* [[Alternative propulsion]]
* [[Compressed air battery]]
* [[Compressed air]] (other uses)
* [[Compressed air vehicle]] (CAV)
* [[Compressed natural gas]] cylinders
* [[Cryogenic energy storage]]
* [[Fireless locomotive]]
* [[Grid energy storage]]
* [[Hydraulic accumulator]]
* [[Liquid nitrogen vehicle]]
* [[List of energy storage projects]]
* [[Pneumatics]]
* [[United States Department of Energy International Energy Storage Database]]
* [[Vehicle-to-grid]]
* [[Zero-emissions vehicle]]
 
==References==
 
{{Reflist|colwidth=30em}}
 
== External links ==
* Compressed Air System of Paris – technical notes [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris.html Part 1] [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris-Part-2.html Part 2] [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris-Part-3.html Part 3] [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris-Part-4.html Part 4] [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris-Part-5.html Part 5] [http://chestofbooks.com/crafts/scientific-american/sup6/The-Compressed-Air-System-Of-Paris-Part-6.html Part 6 ] (Special supplement, Scientific American, 1921)
* [http://www.sandia.gov/media/NewsRel/NR2001/norton.htm Solution to some of country’s energy woes might be little more than hot air] ([[Sandia National Labs]], [[United States Department of Energy|DoE]]).
* MSNBC article, [http://www.msnbc.msn.com/id/10695864/ Cities to Store Wind Power for Later Use], January 4, 2006
* [http://www.economist.com/science/displaystory.cfm?story_id=9539806 Power storage: Trapped wind]
* [http://www.businessweek.com/magazine/content/07_41/b4053092.htm Catching The Wind In A Bottle A group of Midwest utilities is building a plant that will store excess wind power underground]
* [http://query.nytimes.com/gst/fullpage.html?res=9D0CEEDE103DF93AA1575AC0A967958260&sec=&spon=&pagewanted=print New York Times Article: Technology; Using Compressed Air To Store Up Electricity]
* [http://saurorja.org/2012/06/18/compressed-air-energy-storage-entropy-and-efficiency/ Compressed Air Energy Storage, Entropy and Efficiency]
 
 
{{DEFAULTSORT:Compressed-Air Energy Storage}}
[[Category:Energy storage]]
[[Category:Compressed air power]]

Revision as of 18:23, 11 December 2013

Template:Lead too short Template:Use mdy dates I'm Robin and was born on 14 August 1971. My hobbies are Disc golf and Hooping.

My web site - http://www.hostgator1centcoupon.info/

A pressurized air tank used to start a diesel generator set in Paris Metro

Compressed air energy storage (CAES) is a way to store energy generated at one time for use at another time. At utility scale, energy generated during periods of low energy demand (off-peak) can be released to meet higher demand (peak load) periods.[1]

Types

Compression of air generates heat; the air is warmer after compression. Expansion requires heat. If no extra heat is added, the air will be much colder after expansion. If the heat generated during compression can be stored and used during expansion, the efficiency of the storage improves considerably.[2] There are three ways in which a CAES system can deal with the heat. Air storage can be adiabatic, diabatic, or isothermal.

Adiabatic

Adiabatic storage retains the heat produced by compression and returns it to the air when the air is expanded to generate power. This is a subject of ongoing study, with no utility scale plants as of 2010, but a German project ADELE is planned to enter development in 2013.[3] The theoretical efficiency of adiabatic storage approaches 100% with perfect insulation, but in practice round trip efficiency is expected to be 70%.[4] Heat can be stored in a solid such as concrete or stone, or more likely in a fluid such as hot oil (up to 300 °C) or molten salt solutions (600 °C).

Diabatic

Diabatic storage dissipates much of the heat of compression with intercoolers (thus approaching isothermal compression) into the atmosphere as waste; essentially wasting, thereby, the renewable energy used to perform the work of compression. Upon removal from storage, the temperature of this compressed air is the one indicator of the amount of stored energy that remains in this air. Consequently, if the air temperature is low for the energy recovery process, the air must be substantially re-heated prior to expansion in the turbine to power a generator. This reheating can be accomplished with a natural gas fired burner for utility grade storage or with a heated metal mass. As recovery is often most needed when renewable sources are quiescent, fuel must be burned to make up for the wasted heat. This degrades the efficiency of the storage-recovery cycle; and while this approach is relatively simple, the burning of fuel adds to the cost of the recovered electrical energy and compromises the ecological benefits associated with most renewable energy sources. Nevertheless, this is thus far the only system which has been implemented commercially.

The McIntosh, Alabama CAES plant requires 2.5 MJ of electricity and 1.2 MJ lower heating value (LHV) of gas for each megajoule of energy output, corresponding to an energy recovery efficiency of about 27%.[5] A General Electric 7FA 2x1 combined cycle plant, one of the most efficient natural gas plants in operation, uses 6.6 MJ (LHV) of gas per kW·h generated,[6] a 54% thermal efficiency compared to the McIntosh 6.8 MJ, at 27% thermal efficiency.

Isothermal

Isothermal compression and expansion approaches attempt to maintain operating temperature by constant heat exchange to the environment. They are only practical for low power levels, without very effective heat exchangers. The theoretical efficiency of isothermal energy storage approaches 100% for perfect heat transfer to the environment. In practice neither of these perfect thermodynamic cycles are obtainable, as some heat losses are unavoidable.

Other

One implementation of isothermal CAES, uses high, medium and low pressure pistons in series, with each stage followed by an airblast venturi pump that draws ambient air over an air-to-air (or air-to-seawater) heat exchanger between each expansion stage. Early compressed air torpedo designs used a similar approach, substituting seawater for air. The venturi warms the exhaust of the preceding stage and admits this preheated air to the following stage. This approach was widely adopted in various compressed air vehicles such as H. K. Porter, Inc's mining locomotives[7] and trams.[8] Here the heat of compression is effectively stored in the atmosphere (or sea) and returned later on.

Compressors and expanders

Compression can be done with electrically powered turbo-compressors and expansion with turbo 'expanders'[9] or air engines driving electrical generators to produce electricity.

Storage

The storage vessel is often an underground cavern created by solution mining (salt is dissolved in water for extraction)[10] or by utilizing an abandoned mine; use of porous rock formations such as those in which reservoirs of natural gas are found has also been studied.[11] Plants operate on a daily cycle, charging at night and discharging during the day. Heating of the compressed air using natural gas or geothermal heat to increase the amount of energy being extracted has been studied by the Pacific Northwest National Laboratory[11]

Compressed air energy storage can also be employed on a smaller scale such as exploited by air cars and air-driven locomotives, and also by the use of high-strength carbon-fiber air storage tanks. However, when compressed air is stored at room temperature this stored air, in general, contains the same amount of energy per pound as uncompressed room temperature air. The considerable amount of energy used to compress this air is not stored there if the air is allowed to reduce to room temperature. Therefore, to obtain substantial energy from the expansion of this stored room temperature compressed air a heat reservoir must be provided to supply the needed energy. This can be challenging in mobile applications.

Specialized applications

Template:Patent, awarded in January 2013, describes a turbo-expander machine that offers both high efficiency energy recovery and high power output. The turbo-expander utilizes no fuel combustion, but instead is powered by the recovery of atmospheric heat (e.g., the wasted heat of compression as described in the Diabatic classification). When combined with renewable energy powered air compression, such an energy recovery machine would enable a compressed air storage and recovery methodology that is both cost-effective and eco-friendly.

History

City-wide compressed air energy systems have been built since 1870.[12] Cities such as Paris, France; Birmingham, England; Dresden, Rixdorf and Offenbach, Germany and Buenos Aires, Argentina installed such systems. Victor Popp constructed the first systems to power clocks by sending a pulse of air every minute to change their pointer arms. They quickly evolved to deliver power to homes and industry.[13] As of 1896, the Paris system had 2.2 MW of generation distributed at 550 kPa in 50 km of air pipes for motors in light and heavy industry. Usage was measured by meters.[12] The systems were the main source of house-delivered energy in these days and also powered the machines of dentists, seamstresses, printing facilities and bakeries.

  • 1978 – The first utility-scale compressed air energy storage project was the 290 megawatt Huntorf plant in Germany using a salt dome.
  • 1991 – A 110 megawatt plant with a capacity of 26 hours was built in McIntosh, Alabama (1991). The Alabama facility's $65 million cost works out to $550 per Kilowatt hour of capacity, using a 19 million cubic foot solution mined salt cavern to store air at up to 1100 psi. Although the compression phase is approximately 82% efficient, the expansion phase requires combustion of natural gas at one third the rate of a gas turbine producing the same amount of electricity.[14][15][16]
  • November 2009 – The US Department of energy awards $24.9 million in matching funds for phase one of a 300 MW, $356 million Pacific Gas and Electric CAES installation utilizing a saline porous rock formation being developed near Bakersfield in Kern County, California. Goals of the project is to build and validate an advanced design.[17]
  • December, 2010 – DOE provides $29.4 million in funding to conduct preliminary work on a 150 MW salt-based CAES project being developed by Iberdrola USA in Watkins Glen, New York. The goal is to incorporate smart grid technology to balance renewable intermittent energy sources.[17][18]
  • December, 2012 – General Compression completes construction of a 2MW near-isothermal CAES project in Gaines, TX; the world's third CAES project. The project uses no fuel and has 500MWh of storage capacity. [19]
  • 2013 (projected) – The first adiabatic CAES project, a 200 megawatt facility called ADELE, is planned for construction in Germany.
  • 2016 (projected) – Apex has planned a CAES plant for Anderson County, Texas to go online in 2016[20]

Storage thermodynamics

In order to achieve a near thermodynamic reversible process so that most of the energy is saved in the system and can be retrieved, and losses are kept negligible, a near reversible isothermal process or an isentropic process is desired.[2]

Isothermal storage

In an isothermal compression process, the gas in the system is kept at a constant temperature throughout. This necessarily requires removal of heat from the gas, which otherwise would experience a temperature rise due to the energy that has been added to the gas by the compressor. This heat removal can be achieved by heat exchangers (intercooling) between subsequent stages in the compressor. To avoid wasted energy, the intercoolers must be optimised for high heat transfer and low pressure drop. Naturally this is only an approximation to an isothermal compression, since the heating and compression occurs in discrete phases. Some smaller compressors can approximate isothermal compression even without intercooling, due to the relatively high ratio of surface area to volume of the compression chamber and the resulting improvement in heat dissipation from the compressor body itself.

To obtain a perfect isothermal storage process, the process must be reversible. This requires that the heat transfer between the surroundings and the gas occur over an infinitesimally small temperature difference. In that case, there is no exergy loss in the heat transfer process, and so the compression work can be completely recovered as expansion work: 100% storage efficiency. However, in practice, there is always a temperature difference in any heat transfer process, and so all practical energy storage obtains efficiencies significantly lower than 100%.

To estimate the compression/expansion work in an isothermal process, it may be assumed that the compressed air obeys the ideal gas law,

.

From a process from an initial state A to a final state B, with absolute temperature constant, one finds the work required for compression (negative) or done by the expansion (positive), to be

,

where , and so, . Here, is the absolute pressure, is the volume of the vessel, is the amount of substance of gas (mol) and is the ideal gas constant.

Example

How much energy can be stored in a 1 m³ storage vessel at a pressure of 70 bar (7.0 MPa), if the ambient pressure is 1 bar (0.1 MPa). In this case, the process work is

= 7.0 MPa × 1 m³ × ln(0.1 MPa / 7.0 MPa) = -29.7 MJ.

The negative sign means that work is done on the gas by the surroundings. Process irreversibilities (such as in heat transfer) will result in less energy being recovered from the expansion process than is required for the compression process. If the environment is at a constant temperature, for example, the thermal resistance in the intercoolers will mean that the compression occurs at a temperature somewhat higher than the ambient temperature, and the expansion will occur at a temperature somewhat lower than ambient temperature. So a perfect isothermal storage system is impossible to achieve.

Adiabatic (isentropic) storage

An adiabatic process is one where there is no heat transfer between the fluid and the surroundings: the system is insulated against heat transfer. If the process is furthermore internally reversible (smooth, slow and frictionless, to the ideal limit) then it will additionally be isentropic.

An adiabatic storage system does away with the intercooling during the compression process, and simply allows the gas to heat up during compression, and likewise to cool down during expansion. This is attractive, since the energy losses associated with the heat transfer are avoided, but the downside is that the storage vessel must be insulated against heat loss. It should also be mentioned that real compressors and turbines are not isentropic, but instead have an isentropic efficiency of around 85%, with the result that round-trip storage efficiency for adiabatic systems is also considerably less than perfect.

Large storage system thermodynamics

Energy storage systems often use large underground caverns. This is the preferred system design, due to the very large volume, and thus the large quantity of energy that can be stored with only a small pressure change. The cavern space can be easily insulated, compressed adiabatically with little temperature change (approaching a reversible isothermal system) and heat loss (approaching an isentropic system). This advantage is in addition to the low cost of constructing the gas storage system, using the underground walls to assist in containing the pressure.

Recently there have been developed undersea insulated air bags, with similar thermodynamic properties to large underground cavern storage.[21]

Practical constraints in transportation

In order to use air storage in vehicles or aircraft for practical land or air transportation, the energy storage system must be compact and lightweight. Energy density is the engineering term that defines these desired qualities.

Energy density and efficiency

As explained in the thermodynamics of gas storage section above, compressing air heats it and expanding it cools it. Therefore practical air engines require heat exchangers in order to avoid excessively high or low temperatures and even so don't reach ideal constant temperature conditions, or ideal thermal insulation.

Nevertheless, as stated above, it is useful to describe the maximum energy storable using the isothermal case, which works out to about 100 kJ/m3 [ ln(PA/PB)].

Thus if 1.0 m3 of ambient air is very slowly compressed into a 5 L bottle at 20 MPa (200 bar), the potential energy stored is 530 kJ. A highly efficient air motor can transfer this into kinetic energy if it runs very slowly and manages to expand the air from its initial 20 MPa pressure down to 100 kPa (bottle completely "empty" at ambient pressure). Achieving high efficiency is a technical challenge both due to heat loss to the ambient and to unrecoverable internal gas heat.[22] If the bottle above is emptied to 1 MPa, the extractable energy is about 300 kJ at the motor shaft.

A standard 20 MPa, 5 L steel bottle has a mass of 7.5 kg, a superior one 5 kg. High-tensile strength fibers such as carbon-fiber or Kevlar can weigh below 2 kg in this size, consistent with the legal safety codes. One cubic meter of air at 20 °C has a mass of 1.204 kg at standard temperature and pressure.[23] Thus, theoretical energy densities are from roughly 70 kJ/kg at the motor shaft for a plain steel bottle to 180 kJ/kg for an advanced fiber-wound one, whereas practical achievable energy densities for the same containers would be from 40 to 100 kJ/kg.

Comparison with batteries

Advanced fiber-reinforced bottles are comparable to the rechargeable lead-acid battery in terms of energy density. Batteries provide nearly constant voltage over their entire charge level, whereas the pressure varies greatly while using a pressure vessel from full to empty. It is technically challenging to design air engines to maintain high efficiency and sufficient power over a wide range of pressures. Compressed air can transfer power at very high flux rates, which meets the principal acceleration and deceleration objectives of transportation systems, particularly for hybrid vehicles.

Compressed air systems have advantages over conventional batteries including longer lifetimes of pressure vessels and lower material toxicity. Newer battery designs such as those based on Lithium Iron Phosphate chemistry suffer from neither of these problems. Compressed air costs are potentially lower; however advanced pressure vessels are costly to develop and safety-test and at present are more expensive than mass-produced batteries.

As with electric storage technology, compressed air is only as "clean" as the source of the energy that it stores. Life cycle assessment addresses the question of overall emissions from a given energy storage technology combined with a given mix of generation on a power grid.

Safety

As with most technologies, compressed air has safety concerns, mainly catastrophic tank rupture. Safety codes make this a rare occurrence at the cost of higher weight and additional safety features such as pressure relief valves. Codes may limit the legal working pressure to less than 40% of the rupture pressure for steel bottles (safety factor of 2.5), and less than 20% for fiber-wound bottles (safety factor of 5). Commercial designs adopt the ISO 11439 standard.[24] High pressure bottles are fairly strong so that they generally do not rupture in vehicle crashes.

Vehicle applications

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church.

History

Air engines have been used since the 19th century to power mine locomotives, pumps, drills and trams, via centralized, city-level, distribution. Racecars use compressed air to start their internal combustion engine (ICE), and large Diesel engines may have starting pneumatic motors.

A compressed air locomotive by H. K. Porter, Inc., in use at the Homestake Mine between 1928 and 1961.

Engine

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church.

A compressed air engine uses the expansion of compressed air to drive the pistons of an engine, turn the axle, or to drive a turbine.

The following methods can increase efficiency:

  • A continuous expansion turbine at high efficiency
  • Multiple expansion stages
  • Use of waste heat, notably in a hybrid heat engine design
  • Use of environmental heat

A highly efficient arrangement uses high, medium and low pressure pistons in series, with each stage followed by an airblast venturi that draws ambient air over an air-to-air heat exchanger. This warms the exhaust of the preceding stage and admits this preheated air to the following stage. The only exhaust gas from each stage is cold air which can be as cold as Template:Convert; the cold air may be used for air conditioning in a car.[8]

Additional heat can be supplied by burning fuel as in 1904 for Whitehead's torpedoes.[25] This improves the range and speed available for a given tank volume at the cost of the additional fuel.

Cars

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church.

Since about 1990 several companies have claimed to be developing compressed air cars, but none are available. Typically the main claimed advantages are: no roadside pollution, low cost, use of cooking oil for lubrication, and integrated air conditioning.

The time required to refill a depleted tank is important for vehicle applications. "Volume transfer" moves pre-compressed air from a stationary tank to the vehicle tank almost instantaneously. Alternatively, a stationary or on-board compressor can compress air on demand, possibly requiring several hours.

Types of systems

Hybrid systems

Brayton cycle engines compress and heat air with a fuel suitable for an internal combustion engine. For example, natural gas or biogas heat compressed air, and then a conventional gas turbine engine or the rear portion of a jet engine expands it to produce work.

Compressed air engines can recharge an electric battery. The apparently defunct Energine promoted its Pne-PHEV or Pneumatic Plug-in Hybrid Electric Vehicle-system)Potter or Ceramic Artist Truman Bedell from Rexton, has interests which include ceramics, best property developers in singapore developers in singapore and scrabble. Was especially enthused after visiting Alejandro de Humboldt National Park..[26]

Existing hybrid systems

Huntorf, Germany in 1978, and McIntosh, Alabama, U.S. in 1991 commissioned hybrid power plants.[9][27] Both systems use off-peak energy for air compression. The McIntosh plant achieves its 24-hour operating cycle by burning a natural gas/compressed air mix.

Future hybrid systems

The Iowa Stored Energy Park (ISEP) will use aquifer storage rather than cavern storage. The displacement of water in the aquifer results in regulation of the air pressure by the constant hydrostatic pressure of the water. A spokesperson for ISEP claims, "you can optimize your equipment for better efficiency if you have a constant pressure."[27] Power output of the McIntosh and Iowa systems is in the range of 2–300 MW.[28]

Additional facilities are under development in Norton, Ohio. FirstEnergy, an Akron, Ohio electric utility obtained development rights to the 2,700 MW Norton project in November, 2009.[29]

Lake or ocean storage

Deep water in lakes and the ocean can provide pressure without requiring high-pressure vessels or drilling into salt caverns or aquifers.[30] The air goes into inexpensive, flexible containers such as plastic bags below in deep lakes or off sea coasts with steep drop-offs. Obstacles include the limited number of suitable locations and the need for high-pressure pipelines between the surface and the containers. Since the containers would be very inexpensive, the need for great pressure (and great depth) may not be as important. A key benefit of systems built on this concept is that charge and discharge pressures are a constant function of depth. Carnot inefficiencies can thereby be reduced in the power plant. Carnot efficiency can be increased by using multiple charge and discharge stages and using inexpensive heat sources and sinks such as cold water from rivers or hot water from solar ponds. Ideally, the system must be very clever—for example, by cooling air before pumping on summer days. It must be engineered to avoid inefficiency, such as wasteful pressure changes caused by inadequate piping diameter.[31]

A nearly isobaric solution is possible if the compressed gas is used to drive a hydroelectric system. However, this solution requires large pressure tanks located on land (as well as the underwater air bags). Also, hydrogen gas is the preferred fluid, since other gases suffer from substantial hydrostatic pressures at even relatively modest depths (such as 500 meters).

E.ON, one of Europe's leading power and gas companies, has provided €1.4 million (£1.1 million) in funding to develop undersea air storage bags.[32] [33] Hydrostor in Canada is developing a commercial system of underwater storage "accumulators" for compressed air energy storage, starting at the 1 to 4 MW scale.[34]

See also

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References

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External links

  1. Wild, Matthew, L. Wind Drives Growing Use of Batteries, New York Times, July 28, 2010, pp.B1.
  2. 2.0 2.1 Gies, Erica. Global Clean Energy: A Storage Solution Is in the Air, International Herald Tribune, October 1, 2012. Retrieved from NYTimes.com website, March 19, 2013.
  3. Template:Cite web
  4. Template:Cite web
  5. http://my.epri.com/portal/server.pt?Abstract_id=TR-101751-V2
  6. http://www.westgov.org/wieb/electric/Transmission%20Protocol/SSG-WI/pnw_5pp_02.pdf
  7. Compressed-Air Propulsion
  8. 8.0 8.1 3-stage propulsion with intermediate heating
  9. 9.0 9.1 Template:Cite web
  10. http://www.answers.com/topic/solution-mining?cat=technology ; http://www.saltinstitute.org/12.html
  11. 11.0 11.1 Template:Cite web
  12. 12.0 12.1 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  13. Technische Mislukkingen by Lex Veldhoen & Jan van den Ende
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  15. Many property agents need to declare for the PIC grant in Singapore. However, not all of them know find out how to do the correct process for getting this PIC scheme from the IRAS. There are a number of steps that you need to do before your software can be approved.

    Naturally, you will have to pay a safety deposit and that is usually one month rent for annually of the settlement. That is the place your good religion deposit will likely be taken into account and will kind part or all of your security deposit. Anticipate to have a proportionate amount deducted out of your deposit if something is discovered to be damaged if you move out. It's best to you'll want to test the inventory drawn up by the owner, which can detail all objects in the property and their condition. If you happen to fail to notice any harm not already mentioned within the inventory before transferring in, you danger having to pay for it yourself.

    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

    Have handed an trade examination i.e Widespread Examination for House Brokers (CEHA) or Actual Property Agency (REA) examination, or equal; Exclusive brokers are extra keen to share listing information thus making certain the widest doable coverage inside the real estate community via Multiple Listings and Networking. Accepting a severe provide is simpler since your agent is totally conscious of all advertising activity related with your property. This reduces your having to check with a number of agents for some other offers. Price control is easily achieved. Paint work in good restore-discuss with your Property Marketing consultant if main works are still to be done. Softening in residential property prices proceed, led by 2.8 per cent decline within the index for Remainder of Central Region

    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

    To achieve the very best outcomes, you must be always updated on market situations, including past transaction information and reliable projections. You could review and examine comparable homes that are currently available in the market, especially these which have been sold or not bought up to now six months. You'll be able to see a pattern of such report by clicking here It's essential to defend yourself in opposition to unscrupulous patrons. They are often very skilled in using highly unethical and manipulative techniques to try and lure you into a lure. That you must also protect your self, your loved ones, and personal belongings as you'll be serving many strangers in your home. Sign a listing itemizing of all of the objects provided by the proprietor, together with their situation. HSR Prime Recruiter 2010
  16. Many property agents need to declare for the PIC grant in Singapore. However, not all of them know find out how to do the correct process for getting this PIC scheme from the IRAS. There are a number of steps that you need to do before your software can be approved.

    Naturally, you will have to pay a safety deposit and that is usually one month rent for annually of the settlement. That is the place your good religion deposit will likely be taken into account and will kind part or all of your security deposit. Anticipate to have a proportionate amount deducted out of your deposit if something is discovered to be damaged if you move out. It's best to you'll want to test the inventory drawn up by the owner, which can detail all objects in the property and their condition. If you happen to fail to notice any harm not already mentioned within the inventory before transferring in, you danger having to pay for it yourself.

    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

    Have handed an trade examination i.e Widespread Examination for House Brokers (CEHA) or Actual Property Agency (REA) examination, or equal; Exclusive brokers are extra keen to share listing information thus making certain the widest doable coverage inside the real estate community via Multiple Listings and Networking. Accepting a severe provide is simpler since your agent is totally conscious of all advertising activity related with your property. This reduces your having to check with a number of agents for some other offers. Price control is easily achieved. Paint work in good restore-discuss with your Property Marketing consultant if main works are still to be done. Softening in residential property prices proceed, led by 2.8 per cent decline within the index for Remainder of Central Region

    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

    To achieve the very best outcomes, you must be always updated on market situations, including past transaction information and reliable projections. You could review and examine comparable homes that are currently available in the market, especially these which have been sold or not bought up to now six months. You'll be able to see a pattern of such report by clicking here It's essential to defend yourself in opposition to unscrupulous patrons. They are often very skilled in using highly unethical and manipulative techniques to try and lure you into a lure. That you must also protect your self, your loved ones, and personal belongings as you'll be serving many strangers in your home. Sign a listing itemizing of all of the objects provided by the proprietor, together with their situation. HSR Prime Recruiter 2010
  17. 17.0 17.1 Many property agents need to declare for the PIC grant in Singapore. However, not all of them know find out how to do the correct process for getting this PIC scheme from the IRAS. There are a number of steps that you need to do before your software can be approved.

    Naturally, you will have to pay a safety deposit and that is usually one month rent for annually of the settlement. That is the place your good religion deposit will likely be taken into account and will kind part or all of your security deposit. Anticipate to have a proportionate amount deducted out of your deposit if something is discovered to be damaged if you move out. It's best to you'll want to test the inventory drawn up by the owner, which can detail all objects in the property and their condition. If you happen to fail to notice any harm not already mentioned within the inventory before transferring in, you danger having to pay for it yourself.

    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

    Have handed an trade examination i.e Widespread Examination for House Brokers (CEHA) or Actual Property Agency (REA) examination, or equal; Exclusive brokers are extra keen to share listing information thus making certain the widest doable coverage inside the real estate community via Multiple Listings and Networking. Accepting a severe provide is simpler since your agent is totally conscious of all advertising activity related with your property. This reduces your having to check with a number of agents for some other offers. Price control is easily achieved. Paint work in good restore-discuss with your Property Marketing consultant if main works are still to be done. Softening in residential property prices proceed, led by 2.8 per cent decline within the index for Remainder of Central Region

    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

    To achieve the very best outcomes, you must be always updated on market situations, including past transaction information and reliable projections. You could review and examine comparable homes that are currently available in the market, especially these which have been sold or not bought up to now six months. You'll be able to see a pattern of such report by clicking here It's essential to defend yourself in opposition to unscrupulous patrons. They are often very skilled in using highly unethical and manipulative techniques to try and lure you into a lure. That you must also protect your self, your loved ones, and personal belongings as you'll be serving many strangers in your home. Sign a listing itemizing of all of the objects provided by the proprietor, together with their situation. HSR Prime Recruiter 2010
  18. Many property agents need to declare for the PIC grant in Singapore. However, not all of them know find out how to do the correct process for getting this PIC scheme from the IRAS. There are a number of steps that you need to do before your software can be approved.

    Naturally, you will have to pay a safety deposit and that is usually one month rent for annually of the settlement. That is the place your good religion deposit will likely be taken into account and will kind part or all of your security deposit. Anticipate to have a proportionate amount deducted out of your deposit if something is discovered to be damaged if you move out. It's best to you'll want to test the inventory drawn up by the owner, which can detail all objects in the property and their condition. If you happen to fail to notice any harm not already mentioned within the inventory before transferring in, you danger having to pay for it yourself.

    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

    Have handed an trade examination i.e Widespread Examination for House Brokers (CEHA) or Actual Property Agency (REA) examination, or equal; Exclusive brokers are extra keen to share listing information thus making certain the widest doable coverage inside the real estate community via Multiple Listings and Networking. Accepting a severe provide is simpler since your agent is totally conscious of all advertising activity related with your property. This reduces your having to check with a number of agents for some other offers. Price control is easily achieved. Paint work in good restore-discuss with your Property Marketing consultant if main works are still to be done. Softening in residential property prices proceed, led by 2.8 per cent decline within the index for Remainder of Central Region

    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

    To achieve the very best outcomes, you must be always updated on market situations, including past transaction information and reliable projections. You could review and examine comparable homes that are currently available in the market, especially these which have been sold or not bought up to now six months. You'll be able to see a pattern of such report by clicking here It's essential to defend yourself in opposition to unscrupulous patrons. They are often very skilled in using highly unethical and manipulative techniques to try and lure you into a lure. That you must also protect your self, your loved ones, and personal belongings as you'll be serving many strangers in your home. Sign a listing itemizing of all of the objects provided by the proprietor, together with their situation. HSR Prime Recruiter 2010
  19. Template:Cite web
  20. Many property agents need to declare for the PIC grant in Singapore. However, not all of them know find out how to do the correct process for getting this PIC scheme from the IRAS. There are a number of steps that you need to do before your software can be approved.

    Naturally, you will have to pay a safety deposit and that is usually one month rent for annually of the settlement. That is the place your good religion deposit will likely be taken into account and will kind part or all of your security deposit. Anticipate to have a proportionate amount deducted out of your deposit if something is discovered to be damaged if you move out. It's best to you'll want to test the inventory drawn up by the owner, which can detail all objects in the property and their condition. If you happen to fail to notice any harm not already mentioned within the inventory before transferring in, you danger having to pay for it yourself.

    In case you are in search of an actual estate or Singapore property agent on-line, you simply should belief your intuition. It's because you do not know which agent is nice and which agent will not be. Carry out research on several brokers by looking out the internet. As soon as if you end up positive that a selected agent is dependable and reliable, you can choose to utilize his partnerise in finding you a home in Singapore. Most of the time, a property agent is taken into account to be good if he or she locations the contact data on his website. This may mean that the agent does not mind you calling them and asking them any questions relating to new properties in singapore in Singapore. After chatting with them you too can see them in their office after taking an appointment.

    Have handed an trade examination i.e Widespread Examination for House Brokers (CEHA) or Actual Property Agency (REA) examination, or equal; Exclusive brokers are extra keen to share listing information thus making certain the widest doable coverage inside the real estate community via Multiple Listings and Networking. Accepting a severe provide is simpler since your agent is totally conscious of all advertising activity related with your property. This reduces your having to check with a number of agents for some other offers. Price control is easily achieved. Paint work in good restore-discuss with your Property Marketing consultant if main works are still to be done. Softening in residential property prices proceed, led by 2.8 per cent decline within the index for Remainder of Central Region

    Once you place down the one per cent choice price to carry down a non-public property, it's important to accept its situation as it is whenever you move in – faulty air-con, choked rest room and all. Get round this by asking your agent to incorporate a ultimate inspection clause within the possibility-to-buy letter. HDB flat patrons routinely take pleasure in this security net. "There's a ultimate inspection of the property two days before the completion of all HDB transactions. If the air-con is defective, you can request the seller to repair it," says Kelvin.

    15.6.1 As the agent is an intermediary, generally, as soon as the principal and third party are introduced right into a contractual relationship, the agent drops out of the image, subject to any problems with remuneration or indemnification that he could have against the principal, and extra exceptionally, against the third occasion. Generally, agents are entitled to be indemnified for all liabilities reasonably incurred within the execution of the brokers´ authority.

    To achieve the very best outcomes, you must be always updated on market situations, including past transaction information and reliable projections. You could review and examine comparable homes that are currently available in the market, especially these which have been sold or not bought up to now six months. You'll be able to see a pattern of such report by clicking here It's essential to defend yourself in opposition to unscrupulous patrons. They are often very skilled in using highly unethical and manipulative techniques to try and lure you into a lure. That you must also protect your self, your loved ones, and personal belongings as you'll be serving many strangers in your home. Sign a listing itemizing of all of the objects provided by the proprietor, together with their situation. HSR Prime Recruiter 2010
  21. Energy bags under the sea to be tested in 2011(Cleantechnica website). See in sections below.
  22. Heat loss of practical systems is explained in the #Thermodynamics of heat storage section.
  23. Air – Density and Specific Weight, The Engineering Toolbox
  24. Gas cylinders – High pressure cylinders for the on-board storage of natural gas as a fuel for automotive vehicles
  25. A History of the Torpedo The Early Days
  26. Energine PHEV-system schematic
  27. 27.0 27.1 One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  28. Frequently Asked Questions
  29. http://www.firstenergycorp.com/NewsReleases/2009-11-23%20Norton%20Project.pdf
  30. Template:Cite web
  31. Prior art. Oliver Laing et al. Energy storage for off peak electricity. United States Patent No. 4873828.
  32. Template:Cite web
  33. Template:Cite web
  34. Template:Cite web